Entertainment TV New Cast of 'Charmed' React to Backlash: We Want to Focus on the 'Positivity' of the Show "Charmed" premieres on the CW Sunday, October 14th at 9PM ET. By People Staff Published on October 9, 2018 06:30 PM Share Tweet Pin Email “Charmed” premieres on the CW Sunday, October 14th at 9PM ET. PEOPLE Now airs live, Monday through Friday, from the Meredith offices in New York City. Catch PEOPLE Now every weekday at 12:00 p.m. ET/9 a.m. PT on People.com or on the PeopleTV app on your favorite streaming device. Want even more? Check out clips from previous episodes of PEOPLE Now.