With her St. John days behind her, Angelina Jolie could have another endorsement deal in the works: being the new face of Louis Vuitton. reports that the star has signed on with the venerable French luxury house as their newest star face. Jolie would follow in the fashionable footsteps of stars like Madonna, Jennifer Lopez and Scarlett Johansson (plus luminaries including Bono, Buzz Aldrin, Jim Lovell, Sally Ride and Mikhail Gorbachev), representing the company’s gorgeous bags, clothing and accessories. Jolie has been dipping her toes a bit deeper into the fashion world lately, launching a charitable, high-end jewelry line, Style of Jolie, with Robert Procop. Jolie’s reps could not be reached for immediate comment, and reps for Louis Vuitton had no comment. Tell us: Would you be excited to see Jolie in Louis Vuitton ads?