People.com Lifestyle Style Anne Hathaway's 10 Best White Gowns So Far Before walking down the aisle in custom Valentino, the star had plenty of practice being the center of attention in bride-worthy dresses By Alex Apatoff Alex Apatoff Instagram Twitter Alex Apatoff is the Executive Editor of PEOPLE Digital. She has been with the brand for more than a decade, holding various roles on the Style and Beauty team before becoming the site's Lifestyle Director to coordinate the work across the commerce, evergreen, features and marketing teams. Prior to her role at PEOPLE, Alex worked at Us Weekly (where, among other things, she oversaw the Fashion Police pages) and graduated from Northwestern University with a Bachelors in Journalism. People Editorial Guidelines Published on September 28, 2012 10:00 AM Share Tweet Pin Email 01 of 10 GRECIAN & GORGEOUS Daniele Venturelli/WireImage The Devil Wears Prada, but looks positively angelic at the movie’s 2006 Venice Film Festival premiere in a stunning draped column with a feminine, flowing sleeve accent, plus delicate gems. 02 of 10 GET A LEG UP Sylvain Gaboury/FilmMagic But don’t go thinking the pure hue is always so angelic! Later that year, Anne goes for sexy in a plunging, skin-hugging, flower-accented gown that shows off her mile-long legs at a Keep a Child Alive benefit. 03 of 10 BOW-TIFUL BRIDE Jeff Kravitz/FilmMagic More than five years before tying the knot in Valentino, the actress test drives another white gown by the designer, this one adorned with an oversize bow, at the 2007 Academy Awards. Love it or hate it, it’s easy to understand why her stylist Rachel Zoe is so sure Anne’s wedding dress will be such “a fashion moment.” 04 of 10 TIERS OF JOY Elisabetta A. Villa/WireImage After seeing Anne in another elegant white Valentino creation (made just for her!) at the 2008 Rome Get Smart premiere, we totally understand why she tapped the legendary designer to create her wedding gown. 05 of 10 BLINGED OUT & BRIDAL Jason Merritt/Getty Anne was heavily nominated for her role in Rachel Getting Married in 2009, but at that year’s Screen Actors Guild Awards, she’s the one looking ready to get hitched in a pretty, pristine Azzaro number with sparkling details that highlight her waist and megawatt smile. 06 of 10 AWARD-WORTHY Frazer Harrison/Getty It’ll be hard to top this breathtaking confection, a gown picked out by Giorgio Armani from his Privé line especially for her red carpet appearance at the 2009 Oscars. (The designer dished to InStyle that the color “was meant to match her complexion so it looked like a second skin on her.”) 07 of 10 SOMETHING OLD Dominique Charriau/WireImage Just a few months prior to getting engaged, Anne slips into yet another white Valentino gown. The one she selects for the 2011 Naked Heart Foundation gala is vintage and has a positively bridal vibe thanks to the romantic ruffles, cap sleeves and Stephen Jones floral crown. 08 of 10 MODERN ROMANCE PA Photos/ Landov Normally a fan of floor-skimming dresses and trains, the bride-to-be opts for something a bit shorter: an Alexander McQueen white lace dress at a London party celebrating the One Day premiere in 2011. 09 of 10 WHAT A SPARKLER Everett Collection/Rex USA All white save for just a bit of bling – sounds like a bridal getup to us! At N.Y.C.’s The Dark Knight Rises premiere in 2012, the actress selects a striking and sexy Prabal Gurung number that’s gorgeous from every angle. 10 of 10 SILVER-SCREEN STUNNER A.M.P.A.S./ABC/Getty Two of the biggest moments in an actress’s life: the day she gets married and the day she hosts the Oscars. For the latter in 2011, one of Anne’s seven wardrobe changes includes this chic Givenchy Haute Couture number, accented with minimal Tiffany & Co. gems.