The country duo displays a deeper side on their sobering single

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Love and Theft is getting serious – at least in song. On the duo’s new single “Whiskey on My Breath,” fans may be surprised to hear a melancholy sound from a pair known more for country pop hooks and harmonies.

“Hopefully it will turn a few heads,” Eric Gunderson, 29, tells PEOPLE of the new music. The song, available on iTunes beginning Monday, “has a throwback feel that a lot of people will appreciate,” he adds.

As the leadoff single from the duo’s upcoming third album of the same name (due out Feb. 10), the song is a taste of what’s to come, says bandmate Stephen Barker Liles. “It shows a different side of us and paves the way for what our new album is going to be like,” shares the singer, 30, who co-wrote the tune with five songwriting friends.

With lyrics like “I ain’t afraid of dyin’/But what scares me to death/Is meeting Jesus with whiskey on my breath,” Liles says, “It’s a song with depth that touches below the surface. It’s like the songs that made me fall in love with country music.”

What do you think of Love and Theft’s new tune? Listen first here: