Hottest Celebrity Couples

Smart, sexy and successful, see how these 22 Hollywood power duos – Brad & Angelina! Posh & Becks! – keep it sizzling. By Karen J. Quan

01 of 22

Brad Pitt & Angelina Jolie

Brad Pitt & Angelina Jolie
Chris Polk/WireImage

The parents of four enjoy a rare moment alone, sneaking a few sweet kisses at the 13th Annual Critics' Choice Awards last month. A power couple since hooking up on the set of Mr. amp Mrs. Smith, Jolie recently admitted that she was reluctant to take the role that introduced her to Pitt. "Obviously I'm very glad I did it," she recently said. "It changed my life."

02 of 22

Jennifer Lopez & Marc Anthony

Jennifer Lopez & Marc Anthony
Kevin Mazur/WireImage

After hiding her pregnancy in loose-fitting outfits by Robert Cavalli, the couple finally confirmed that they were expecting during the final stop of their El Cantante tour in Miami, back in November. With twins on the way, Lopez says that "this is a special time in our lives."

03 of 22

Katie Holmes & Tom Cruise

Katie Holmes & Tom Cruise
Shannon Stapleton/Reuters/Landov

Even though the event was in his honor, Cruise treats his wife like royalty as the pair arrive at the Museum of the Moving Image in New York City in November. Holmes then returned the favor, calling him "a constant source of inspiration and love," and serenading him with his Top Gun classic, the Righteous Brothers' "You've Lost That Lovin' Feeling."

04 of 22

Eva Longoria Parker & Tony Parker

Eva Longoria Parker & Tony Parker
AXELLE/BAUER-GRIFFIN

Sneaking in a few kisses between photo ops at last year's SAG Awards, Longoria Parker admits that marriage has turned the actress into a frequent flyer. "He's been coming to the Desperate Housewives set with me since we returned to Los Angeles – just like during the season when I was going to the Spurs games."

05 of 22

Gwen Stefani & Gavin Rossdale

Gwen Stefani & Gavin Rossdale
Cousart-Mullen-Rayne/ JFX

The stylish couple, with the help of their fashion-friendly firstborn, always paints a perfect family picture, especially after young Kingston's christening in Los Angeles last spring. And with another baby on the way, Stefani and Rossdale can look forward to adding to their adorable brood.

06 of 22

Halle Berry & Gabriel Aubry

Halle Berry & Gabriel Aubry

The twosome are welcoming their first child in March, and throughout her pregnancy, Berry's model beau has been a, well, model beau – massaging her feet and satisfying her cravings. As she told Oprah Winfrey in October, "I know he has ability to love me, love our children, and he will do that."

07 of 22

Ellen DeGeneres & Portia DeRossi

Ellen DeGeneres & Portia DeRossi
Jeff Kravitz/FilmMagic

At last year's Emmy Awards in September, Ellen DeGeneres sat hand-in-hand with lady love Portia de Rossi. Despite some bad luck, they've found their soul mates with one another. As de Rossi told The Advocate in 2005, "I really feel not alone for the first time in my life."

08 of 22

Nicole Richie & Joel Madden

Nicole Richie & Joel Madden
Jeff Vespa/WireImage

They may have just welcomed daughter Harlow Winter Kate Madden into the world last month, but the new parents are already teaching their newborn a lesson in generosity. With a few of their closest bear friends, the duo held a meet-and-greet for children in need during their Richie Madden Children's Foundation Holiday Party in December.

09 of 22

Ben Affleck & Jennifer Garner

Ben Affleck & Jennifer Garner
Mark J. Terrill/AP

With just one look, it's no secret that this low-key couple is still very, very much in love! As Garner told InStyle, "You know how as a kid you picture yourself with a tall, handsome husband, and you imagine him cuddling your baby? Ben is like that, like, on crack."

10 of 22

Will Smith & Jada Pinkett Smith

Will Smith & Jada Pinkett Smith
Bryan Bedder/Getty

Poised and glam, Pinkett Smith complements her dapper husband – and keeps close to his heart – at the Los Angeles premiere of his film I Am Legend in December. And after 10 years of marriage, the partnership never gets old. "We are like best friends. And I totally trust Will," she has said.

11 of 22

William H. Macy & Felicity Huffman

William H. Macy & Felicity Huffman
Eric Charbonneau/WireImage

Huffman provides the perfect touch for her husband at the premiere of his film Wild Hogs. No strangers to tasteful PDA, the couple danced the night away at last year's Emmys – and Macy admitted to Redbook that his wife is "very hot and sexy."

12 of 22

Beyoncé & Jay-Z

Beyoncé & Jay-Z
INF

Enjoying a little summer sun, Knowles cozies up to her beau of five years during a tropical getaway in Saint-Tropez. While neither speaks publicly about their relationship, they make no secret of their affection for one another. For the rapper's 38th birthday, the two enjoyed a very romantic celebration in Paris.

13 of 22

Josh Duhamel & Fergie

Josh Duhamel & Fergie
Kevin Mazur/WireImage

He calls her the "crush of a lifetime." She says their engagement made her feel like "the the luckiest girl in the world." They haven't yet revealed details about their upcoming nuptials, but the couple don't plan on rushing to the altar. "We're just enjoying it," Duhamel tells PEOPLE. "It's all great."

14 of 22

Christina Aguilera & Jordan Bratman

Christina Aguilera & Jordan Bratman
INF

Despite her confident, brassy persona, Aguilera – who welcomed son Max Liron Bratman last month – admits that when it comes to Bratman, she's all mush. "[He's] so supportive and amazing through everything. He came with me on the last leg of the tour and he was my support system. ... I gush. I'm a lucky girl."

15 of 22

Keith Urban & Nicole Kidman

Keith Urban & Nicole Kidman
David Anderson Photography/Headpress/Retna

The twosome – who tied the knot in 2006 – only have eyes for each other at the 2007 ARIA Awards in October. And this couple doesn't shy from grand displays of affection: At a Sept. 16 show in Vancouver, Urban dedicated a song to Kidman, professing, "I would not be here tonight playing for you guys if it wasn't for the extraordinary faith and love of my wife."

16 of 22

Rebecca Romijn & Jerry O'Connell

Rebecca Romijn & Jerry O'Connell
Ramey

Planting a sweet kiss on his wife, O'Connell confesses he'd like lots of kids with Romijn, "before she figures out she could do a lot better than me." From what she's told PEOPLE, though, Romijn isn't ditching her badminton buddy anytime soon: "We'll play for four hours a day!"

17 of 22

Demi Moore & Ashton Kutcher

Demi Moore & Ashton Kutcher
SRL/WireImage

Adorned with the perfect accessory, Demi Moore stays connected to husband Ashton Kutcher during the Prada America's Cup Party in Valencia, Spain, last year. Kutcher, who jumped right into the family life with Moore and her three daughters, won kudos from his wife, who told V magazine, "It says a lot about the confidence that he holds within himself as an individual."

18 of 22

Zac Efron & Vanessa Hudgens

Zac Efron & Vanessa Hudgens
Clark Samuels/Startraks

Staying cool in the summer heat, Hudgens shares her treat with her High School Musical costar and boyfriend Efron before an appearance on Good Morning America. "I don't know what it was with Vanessa," Efron said of their sweet start onscreen, "but we kind of clicked from the very beginning."

19 of 22

Heidi Klum & Seal

Heidi Klum & Seal
Johnny Nunez/WireImage

The model (puckering up to her husband of two years, Seal, at a New York City party in June) revealed to Ellen DeGeneres how the happily married parents of three keep the romance alive."We just say, 'Hey baby, 2 o'clock in the attic, 6 o'clock in the closet,'" she said of their impromptu trysts.

20 of 22

Sarah Jessica Parker & Matthew Broderick

Sarah Jessica Parker & Matthew Broderick
George Pimentel/WireImage

A beaming Parker shares a laugh with her husband during the premiere of Parker's new film Smart People at the Sundance Film Festival last month. The secret to maintaining their marriage of 10 years? Keeping things private. Says Parker, "We try not to talk about the relationship. It's not that we're not proud; it's just that's the kiss of death."

21 of 22

Faith Hill & Tim McGraw

Faith Hill & Tim McGraw
Scott Gries/Getty

Sharing a tender moment onstage, the first couple of country heat up the stage at the Fashion Rocks Concert in New York City. After an extensive trek through the U.S. for their Soul2Soul tour, Hill, who enjoyed a surprise 40th birthday in Greece, tells PEOPLE that with McGraw, "We never have to work to be in love."

22 of 22

David & Victoria Beckham

David & Victoria Beckham
Debbie Vanstory/iPhoto

After wrapping up their life in Madrid, David and Victoria Beckham strike the perfect pose in during a welcome-to-L.A. party hosted by BFFs Will Smith and wife Jada, and Tom Cruise and Katie Holmes. Even after almost eight years of marriage, three kids, a mega-million soccer contract and world tours, David still knows how to be romantic. "He's very good at sending flowers and cards," Posh says.

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