Country Goes Glam: ACM's Fashion Stars

Admitting that she's "never worn red before" on the red carpet, one of

the night's performer's stands out in a dramatic red, one-shouldered

Angel Sanchez gown, a VBH clutch and Neil Lane jewels.

The entertainer of the year winner is utterly

feminine in her blush pink, one-shouldered Randi Rahm gown, Mary Norton clutch and Johnathon Arndt jewels.

Supporting entertainer of the year nominee husband Keith Urban, the star steps out in Pierre Hardy sandals and a black L'Wren Scott embroidered gown that's all business in the front – check out that high neck – and a party in the back with a daring cut-out.

Before performing her hit from the Hannah Montana soundtrack, the star hits the red carpet in a bejeweled Monique Lhuillier gown, Cole Haan evening sandals and chandelier earrings.

The always-sexy singer called her golden Zuhair Murad mermaid gown "my favorite dress I've ever worn." Pickler finished off her look with matching YSL platforms, a Daniel Swarovski clutch, Tito Pedrini earrings and a Lucifer vir Honestus citrine ring.

The star skips a gown, picking an origami pleated black minidress and

studded gladiator Jimmy Choo heels instead.

It's the gilded age for the singer-dancer, who celebrates her first-ever ACM win in an art nouveau-inspired beaded Zuhair Murad gown, Stuart Weitzman heels and Martin Katz jewels.

The Sugarland singer is the ultimate urban sophisticate in her plunging steel gray gown and piles of Kimberly McDonald jewels.

The Ghost Whisperer star plays up her glowing skin in a diaphanous white Robert Rodriguez halter gown.

Arriving with her best accessory – boyfriend Blake Shelton – the singer sizzles in an empire-waist red Nicole Miller minidress, a Mary Norton clutch and Ippolita jewelry.

The Victoria's Secret Angel is definitely heavenly in her white Dolce amp Gabbana corset gown and loose waves.

The presenter sets off her dark hair with a white goddess Badgley Mischka gown, embellished with embroidery on the shoulder, and Martin Katz jewels.

Arriving with boyfriend Matthew McConaughey, the model struts her stuff in a sheer-backed white minidress and matching sandals.