All-Time Beautiful Women

Times Named Most Beautiful: 11
Sure, the 40-year-old Oscar winner has flawless skin and perfectly doe-shaped eyes, but it's not when she's staring in the mirror that she feels radiant. "I feel the most beautiful whenever I'm doing things that I love," says Berry. "I love work, I love being around children, I love reading."

Times Named Most Beautiful: 10
"She likes to dress like a normal housewife or mother," says pal and makeup artist Genevieve of the 39-year-old actress. "She doesn't care at all." But despite Roberts's no-fuss approach to her appearance, there's no hiding the megawatt grin that made her America's Sweetheart.

Times Named Most Beautiful: 5
Even a beauty like Aniston, 38, has suffered her moments of low self-esteem. "I was an unfortunate-looking teenager," she says. "I never felt beautiful." Today, she is at peace with her looks – and it shows. "Jennifer has a sex appeal without trying to be overtly sexy," says hairstylist pal Chris McMillan. "She's a golden girl, head to toe."

Times Named Most Beautiful: 5
She's got natural physical gifts aplenty, but the 37-year-old brunette stunner admits she also relies on her stash of potions and lotions to look her best. "I am a complete makeup fiend," she admits. But, says husband Michael Douglas, "Catherine's beauty is her sense of fun and joy in life."

Times Named Most Beautiful: 5
That hair! Those eyes! And – of course – those lips. But Jolie's beauty also comes from within: She's devoted to motherhood (recently adding a fourth child to her family) and has a social conscience.

Times named Most Beautiful: 8
Once a coltish girl with red hair she despised, Kidman, 39, now embraces her flaming locks and 5'10" height. "There's something you hate about looking different and then there's something that it gives you," says the actress. "It makes you develop your personality. Because you don't conform, you have to find different ways of expressing yourself."

Times Named Most Beautiful: 6
"All I really care about is that I'm able to age gracefully and that I don't ever look like a wax figure of myself," says Pfeiffer, 47, who was the cover girl of the first-ever 50 Most Beautiful issue in 1990. So, what does the actress consider her best feature? "My resilience."

Times Named Most Beautiful: 3
Happiness suits Moore, 44, who became a newlywed when she tied the knot with longtime love Ashton Kutcher in September 2005. But then again, says designer pal Donna Karan, "I've never seen her not look good." And the ultra-fit actress – who stays toned by doing yoga – has no problem keeping up with her three daughters.

Times Named Most Beautiful: 7
"She looks like a piece of Mayan sculpture, and her skin is really beautiful," says Monster-in-Law costar Jane Fonda of Lopez, 36. And the multi-hyphenate performer loves to reinvent herself. "She is very involved in her look," says her hairstylist Oribe. "She wants to come up with new things."

See more of PEOPLE's Most Beautiful 2007