Ever stared at Ashlee Simpson and Pete Wentz together and thought, “Wow, I really want to have eye makeup just like. . .Pete?” You aren’t alone, and the Fall Out Boy bassist, one of PEOPLE’s Most Beautiful, gave us a step by step instruction on how to apply guyliner correctly. Check out the always charming Pete and his handy makeup tips by clicking here. And don’t miss the complete coverage of PEOPLE’s Most Beautiful People online, including covergirl Drew Barrymore, stars without makeup and beauties at every age.