1 of 10
NICOLE KIDMAN & KEITH URBAN
plays supportive spouse to hubby – whose nominated video features home movie footage! – in a striped Proenza Schouler gown, bright Pierre Hardy sandals and a ponytail.
2 of 10
“Valentino – a little leather and lace number” Sugarland’s leading lady, who accepted the award for Best Duo Video with her Fia clutch in hand, tells PEOPLE of her look. Why’d she pick it? “We went for something that was fun and had an edge. You know me, I’m all about the sharper edge!” she jokes.
3 of 10
“I wanted something comfortable and easy, something I knew I’d be able to enjoy spending the whole night in,” Lady Antebellum’s frontwoman explains to PEOPLE of choosing her saucy Alexander McQueen dress with hardware-studded belt, Louboutin shoes, Vahan rings and Isharya earrings to fête the group’s nominations.
4 of 10
JUSTIN BIEBER & RASCAL FLATTS
The dreamy gears up for a win by embracing the night’s party vibe (and representing his pop roots!) in a black-and-white ensemble and David Yurman bracelets to join his co-nominees Rascal Flatts.
5 of 10
6 of 10
Nominated for best collaborative video with CMT host Kid Rock, the hits the red carpet in a curve-skimming Catherine Malandrino gown and beaded clutch.
7 of 10
THE BAND PERRY
The nominated siblings spiff up nicely – sister Kimberly sports a sparkling one-shoulder dress and brown accessories, while brothers Neil and Reid go for a dressy-rocker ensemble of tight pants and sharp blazers.
8 of 10
“I’m not a gown girl! I like to show my legs, so I almost always pick short. And I am crazy about the color!” the busy mom says of selecting her striking blue one-shoulder dress, accessorized with a gold clutch and nude pumps.
9 of 10
Is she trading in her tap shoes for cowboy boots? The Broadway star prepares to present in a lovely, lacy gown by Miguelina. “I bought it off the rack,” she tells PEOPLE. “I just thought it was pretty. I’m all about the royal wedding and lace, and I thought, ‘I’m just going to do it!’”
10 of 10
LAURA BELL BUNDY
“This was mid-length and kind of classy – and a little see-through – so I thought, ‘This is for me!’” the country cutie tells PEOPLE of choosing her sweetheart-neckline Jean Fares Couture mini, worn with champagne pumps.
Is Kim Kardashian Really Naming Her Baby Girl Louis Vuitton West? Star Explains Cryptic Instagram
9 Seriously Stylish Coats to Make a Statement In This Winter
See Gwyneth Paltrow's Enormous Engagement Ring from Fiancé Brad Falchuk