Frazer Harrison/Getty
Kathy Ehrich Dowd
April 05, 2013 11:45 AM

John Mayer has found a new partner – on stage, that is.

The musician, who split from Katy Perry last month, will perform with Brad Paisley at the Academy of Country Music Awards this Sunday night at the MGM Grand in Las Vegas, PEOPLE learns exclusively.

Fellow performers for country’s big night include Carrie Underwood, Taylor Swift, Kelly Clarkson, Tim McGraw, Miranda Lambert, Blake Shelton, Jason Aldean, Garth Brooks, Luke Bryan, Kenny Chesney, Eric Church, Hunter Hayes, Jewel, George Strait, Stevie Wonder, Lady Antebellum, Little Big Town, Pistol Annies and The Band Perry.

Newly announced presenters include Faith Hill, Shania Twain, Trisha Yearwood, Gary Allan, Chris Young and Eli Young Band – joining Sheryl Crow, Kaley Cuoco, Keith Urban and more!

PHOTOS: Country Strong: Nashville’s Happily Married Couples

Mayer will hit the road this summer to support Born and Raised, the album he released last May.

The newly single singer, who counts Jennifer Aniston and Jessica Simpson among his exes, shared a bit about his latest breakup with Ellen DeGeneres in an interview that aired Tuesday.

“I’m on the same journey as everyone else,” he said. “Coupling is a tricky thing.”

Now we get to see how he is at duets!

Tune in for the 48th Annual Academy of Country Music Awards, live from the MGM Grand in Las Vegas, April 7 at 8 p.m. on CBS.

PHOTOS: Country Stars Off the Clock

You May Like