January 31, 2011 08:00 PM

Alex Ribeiro/Broadimage

As if Sao Paulo isn’t sizzling enough, some of the world’s hottest models and one very hunky Hollywood actor turned up the heat during Fashion Week in the Brazilian capital. Gisele Bündchen, the face of Colcci, opened the brand’s show to cheers and screams in a sexy bustier and hot pants. Bundchen tells PEOPLE exclusively, “I have walked in the Colcci show six years in a row. I have grown with the brand that started out in jeans and is now a top selling fashion brand throughout Brazil. The show is always fun and I look forward to doing it each year.” And while Victoria’s Secret Angel Alessandra Ambrosio took to the runway in a variety of sexy styles, it was Colcci’s newest face, Ashton Kutcher, who closed out the show, turning up on the runway for a final walk with Bündchen and brand director Jeziel Moraes. And in case Ashton got cold feet strutting his stuff after a hiatus from modeling, he had plenty of support in the front row from his biggest fan — wife Demi Moore, who brought her youngest daughter Tallulah along. The party continued after the show as the couple dined with Gisele and made an appearance at an exclusive party at the Kiss N’ Fly club, where they danced to electronic music. “I’m just a normal guy. I try to know how things work in the countries I go to so I can be as natural as possible,” Ashton told the Folha de São Paulo newspaper. — reporting by Dom Phillips and Charlotte Triggs

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